Cobaltaelectro-catalyzed C–H acyloxylation of aromatic and vinylic amide derivatives at room temperature

Sitdikov R, Nikolaienko P, Meyer L, Verho O (2025)

Publication Type: Journal article

Publication year: 2025

Journal

Chemical Communications Royal Society of Chemistry

DOI: 10.1039/d5cc04394h

Abstract

9wHerein, we report a mild and efficient cobalt-catalyzed electrochemical method for the regioselective C–H acyloxylation of aromatic and vinylic amides, utilizing 8-aminoquinoline as the directing group. Notably, this protocol requires no stoichiometric oxidants and operates at room temperature in an undivided cell setup, providing sustainable access to a diverse set of ortho-acyloxylated products with broad functional group tolerance.

Involved external institutions

Biomedicinskt centrum (BMC) SE Sweden (SE) Forschungszentrum Jülich / Research Centre Jülich (FZJ) DE Germany (DE)

How to cite

APA:

Sitdikov, R., Nikolaienko, P., Meyer, L., & Verho, O. (2025). Cobaltaelectro-catalyzed C–H acyloxylation of aromatic and vinylic amide derivatives at room temperature. Chemical Communications. https://doi.org/10.1039/d5cc04394h

MLA:

Sitdikov, Ruzal, et al. "Cobaltaelectro-catalyzed C–H acyloxylation of aromatic and vinylic amide derivatives at room temperature." Chemical Communications (2025).

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