Low-coordinate calcium peroxide and oxide complexes

Thum S, Schmidt M, Langer J, Harder S (2025)

Publication Type: Journal article

Publication year: 2025

Journal

Chemical Communications Royal Society of Chemistry

DOI: 10.1039/d5cc03340c

Abstract

A CaI synthon with superbulky β-diketiminate ligands (BDI*) and a N22− dianion, [(BDI*)Ca]2(N2), is key to the synthesis of binuclear (BDI*)Ca(μ2-O2)Ca(BDI*) and (BDI*)Ca(μ2-O)Ca(BDI*) complexes. The Ca oxide complex is particularly unstable in solution and was only accessible by a solvent-free reaction between solid [(BDI*)Ca]2(N2) and N2O gas.

Authors with CRIS profile

Stefan Thum Lehrstuhl für Anorganische und Metallorganische Chemie Marcel Schmidt Lehrstuhl für Anorganische und Metallorganische Chemie Jens Langer Lehrstuhl für Anorganische und Metallorganische Chemie Sjoerd Harder Lehrstuhl für Anorganische und Metallorganische Chemie

How to cite

APA:

Thum, S., Schmidt, M., Langer, J., & Harder, S. (2025). Low-coordinate calcium peroxide and oxide complexes. Chemical Communications. https://doi.org/10.1039/d5cc03340c

MLA:

Thum, Stefan, et al. "Low-coordinate calcium peroxide and oxide complexes." Chemical Communications (2025).

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