Domain structure and piezoelectric property of Ba0.85Ca0.15Zr0.1Ti0.9O3 ceramics polarized by pulse-poling method

Nozaki T, Martin A, Webber KG, Nakayama T, Kakimoto Ki (2025)


Publication Language: English

Publication Type: Journal article

Publication year: 2025

Journal

Book Volume: 108

Article Number: e20705

Journal Issue: 10

DOI: 10.1111/jace.20705

Abstract

The domain structures and piezoelectric properties of polycrystalline orthorhombic 0.5(Ba0.7Ca0.3)TiO3‒0.5Ba(Zr0.2Ti0.8)O3 (BCZT50) polarized by various poling methods were investigated. Semiquantitative analysis using a scanning electron microscope revealed that the domain size dD of BCZT50 polarized by alternating current poling (AC-poling, dD = 0.16 µm) and unipolar pulse poling (Uni-poling, dD = 0.16–0.36 µm) were finer than those in samples polarized by conventional direct current poling method (DC-poling, dD = 0.32 µm). Although the domain size of the Uni-poled sample was intermediate among the three different poling methods, the highest piezoelectric charge coefficient d33 of 339 pC/N was achieved by Uni-poling with a peak electric field Epk = 0.50 kV/mm (Erms = 0.29 kV/mm), 20 pulse cycles, and a frequency of 2 Hz. These results are discussed in conjunction with polarization–electric field hysteresis and dielectric properties, indicating that pulse-poling treatment is a promising approach to modify the domain structure and piezoelectric properties of BCZT50.

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APA:

Nozaki, T., Martin, A., Webber, K.G., Nakayama, T., & Kakimoto, K.-i. (2025). Domain structure and piezoelectric property of Ba0.85Ca0.15Zr0.1Ti0.9O3 ceramics polarized by pulse-poling method. Journal of the American Ceramic Society, 108(10). https://doi.org/10.1111/jace.20705

MLA:

Nozaki, Takumi, et al. "Domain structure and piezoelectric property of Ba0.85Ca0.15Zr0.1Ti0.9O3 ceramics polarized by pulse-poling method." Journal of the American Ceramic Society 108.10 (2025).

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