Manifold-Fused Porphyrin-Nanographene Conjugates

Oleszak C, Ritterhoff C, Martin M, Meyer B, Jux N (2024)

Publication Type: Journal article

Publication year: 2024

Journal

Chemistry - A European Journal Wiley

DOI: 10.1002/chem.202403250

Abstract

A library of novel π-extended porphyrin-hexabenzocoronene (HBC) architectures is presented. Two distinct synthetic pathways were utilized to obtain either phenyl- or HBC-fused compounds. Absorption experiments reveal the species’ exciting photophysical and optoelectronic properties. Depending on the degree of π-extension, the number of porphyrins, and their relative position, a decisive change in shape, panchromatic broadening, and red-shifting of the absorption curves is observed. Theoretical studies give more profound insight into the molecule's electronic structures, showing vast decreases in HOMO-LUMO energy gaps.

Authors with CRIS profile

Christoph Oleszak Sonderforschungsbereich 953/3 Synthetische Kohlenstoffallotrope Christian Ritterhoff Interdisziplinäres Zentrum für Molekulare Materialien (ICMM) Max Martin Naturwissenschaftliche Fakultät Bernd Meyer Professur für Computational Chemistry Norbert Jux Interdisziplinäres Zentrum für Molekulare Materialien (ICMM)

How to cite

APA:

Oleszak, C., Ritterhoff, C., Martin, M., Meyer, B., & Jux, N. (2024). Manifold-Fused Porphyrin-Nanographene Conjugates. Chemistry - A European Journal. https://doi.org/10.1002/chem.202403250

MLA:

Oleszak, Christoph, et al. "Manifold-Fused Porphyrin-Nanographene Conjugates." Chemistry - A European Journal (2024).

BibTeX: Download