Accelerating Photostability Evaluation of Perovskite Films through Intelligent Spectral Learning-Based Early Diagnosis

Liu Z, Zhang J, Rao G, Peng Z, Huang Y, Arnold S, Liu B, Deng C, Li C, Li H, Zhi H, Zhang Z, Zhou W, Hauch J, Yan C, Brabec C, Zhao Y (2024)

Publication Type: Journal article

Publication year: 2024

Journal

Pages Range: 662-670

DOI: 10.1021/acsenergylett.3c02666

Abstract

Obtaining highly stable metal-halide perovskites is crucial for the commercialization of perovskite solar cells. However, current methods for evaluating perovskite stability mainly rely on a time-consuming and resource-intensive aging process. Here, we demonstrate a spectral learning-based methodology that enables the prediction of perovskite stability by leveraging the features in photoluminescence and absorption spectra of fresh perovskite films. This methodology circumvents the long-term aging process by combining a custom-developed spectral feature extraction algorithm and an integrated voting machine learning model. By integration of the early diagnosis program with high-throughput experiments, the prediction accuracy for stable perovskites exceeds 86% in 160 fresh samples. The universality is further examined by another batch of 224 fresh samples fabricated through different processing conditions. Finally, the early diagnosis of perovskite films is successfully translated to enhanced stability in perovskite solar cells. Our work provides a new pathway to accelerate the discovery and development of stable perovskite films.

Authors with CRIS profile

Additional Organisation(s)

Involved external institutions

PLA Army Engineering University / 中国人民解放军陆军工程大学 China (CN) University of Electronic Science and Technology of China (UESTC) / 电子科技大学 China (CN)

How to cite

APA:

Liu, Z., Zhang, J., Rao, G., Peng, Z., Huang, Y., Arnold, S.,... Zhao, Y. (2024). Accelerating Photostability Evaluation of Perovskite Films through Intelligent Spectral Learning-Based Early Diagnosis. ACS Energy Letters, 662-670. https://doi.org/10.1021/acsenergylett.3c02666

MLA:

Liu, Ziyi, et al. "Accelerating Photostability Evaluation of Perovskite Films through Intelligent Spectral Learning-Based Early Diagnosis." ACS Energy Letters (2024): 662-670.

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