Light-Induced Dyotropic Rearrangement of Diarylethenes: Scope, Mechanism, and Prospects

Lvov AG, Koffi Kouame E, Khusniyarov M (2023)

Publication Type: Journal article, Review article

Publication year: 2023

Journal

DOI: 10.1002/chem.202301480

Abstract

Irreversible two-photon photorearrangement of 1,2-diarylethenes is a unique process providing access to complex 2a¹,5a-dihydro-5,6-dithiaacenaphthylene (DDA) heterocyclic core. This reaction was serendipitously discovered during studies on photoswitchable diarylethenes and was initially considered as a highly undesired process. However, in recent years, it has been recognized as an efficient photochemical reaction, interesting by itself and as a promising synthetic method for the synthesis of challenging molecules. Herein, we discuss the state-of-the-art in studies on this notable process.

Authors with CRIS profile

Marat Khusniyarov Department Chemie und Pharmazie

Involved external institutions

National Research Irkutsk State Technical University / Иркутский государственный технический университет

Russian Federation (RU)

How to cite

APA:

Lvov, A.G., Koffi Kouame, E., & Khusniyarov, M. (2023). Light-Induced Dyotropic Rearrangement of Diarylethenes: Scope, Mechanism, and Prospects. Chemistry - A European Journal. https://doi.org/10.1002/chem.202301480

MLA:

Lvov, Andrey G., Eric Koffi Kouame, and Marat Khusniyarov. "Light-Induced Dyotropic Rearrangement of Diarylethenes: Scope, Mechanism, and Prospects." Chemistry - A European Journal (2023).

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