Solid state organic amine detection in a photochromic porous metal organic framework

Mallick A, Garai B, Addicoat MA, Petkov PS, Heine T, Banerjee R (2015)

Publication Type: Journal article

Publication year: 2015

Journal

Chemical Science Royal Society of Chemistry

Book Volume: 6

Pages Range: 1420-1425

Journal Issue: 2

DOI: 10.1039/c4sc03224a

Abstract

A new Mg(ii) based photochromic porous metal-organic framework (MOF) has been synthesized bearing naphthalenediimide (NDI) chromophoric unit. This MOF (Mg-NDI) shows instant and reversible solvatochromic behavior in presence of solvents with different polarity. Mg-NDI also exhibits fast and reversible photochromism via radical formation. Due to the presence of electron deficient NDI moiety, this MOF exhibits selective organic amine (electron rich) sensing in solid state. The organic amine detection has been confirmed by photoluminescence quenching experiment and visual color change.

Involved external institutions

National Chemical Laboratory (NCL) IN India (IN) Jacobs University Bremen gGmbH DE Germany (DE)

How to cite

APA:

Mallick, A., Garai, B., Addicoat, M.A., Petkov, P.S., Heine, T., & Banerjee, R. (2015). Solid state organic amine detection in a photochromic porous metal organic framework. Chemical Science, 6(2), 1420-1425. https://doi.org/10.1039/c4sc03224a

MLA:

Mallick, Arijit, et al. "Solid state organic amine detection in a photochromic porous metal organic framework." Chemical Science 6.2 (2015): 1420-1425.

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