Functionalized Metallic 2D Transition Metal Dichalcogenide-Based Solid-State Electrolyte for Flexible All-Solid-State Supercapacitors

Bagheri A, Bellani S, Beydaghi H, Eredia M, Najafi L, Bianca G, Zappia MI, Safarpour M, Najafi M, Mantero E, Sofer Z, Hou G, Pellegrini V, Feng X, Bonaccorso F (2022)

Publication Type: Journal article

Publication year: 2022

Journal

ACS nano American Chemical Society

Book Volume: 16

Pages Range: 16426-16442

Journal Issue: 10

DOI: 10.1021/acsnano.2c05640

Abstract

Highly efficient and durable flexible solid-state supercapacitors (FSSSCs) are emerging as low-cost devices for portable and wearable electronics due to the elimination of leakage of toxic/corrosive liquid electrolytes and their capability to withstand elevated mechanical stresses. Nevertheless, the spread of FSSSCs requires the development of durable and highly conductive solid-state electrolytes, whose electrochemical characteristics must be competitive with those of traditional liquid electrolytes. Here, we propose an innovative composite solid-state electrolyte prepared by incorporating metallic two-dimensional group-5 transition metal dichalcogenides, namely, liquid-phase exfoliated functionalized niobium disulfide (f-NbS2) nanoflakes, into a sulfonated poly(ether ether ketone) (SPEEK) polymeric matrix. The terminal sulfonate groups in f-NbS2nanoflakes interact with the sulfonic acid groups of SPEEK by forming a robust hydrogen bonding network. Consequently, the composite solid-state electrolyte is mechanically/dimensionally stable even at a degree of sulfonation of SPEEK as high as 70.2%. At this degree of sulfonation, the mechanical strength is 38.3 MPa, and thanks to an efficient proton transport through the Grotthuss mechanism, the proton conductivity is as high as 94.4 mS cm-1at room temperature. To elucidate the importance of the interaction between the electrode materials (including active materials and binders) and the solid-state electrolyte, solid-state supercapacitors were produced using SPEEK and poly(vinylidene fluoride) as proton conducting and nonconducting binders, respectively. The use of our solid-state electrolyte in combination with proton-conducting SPEEK binder and carbonaceous electrode materials (mixture of activated carbon, single/few-layer graphene, and carbon black) results in a solid-state supercapacitor with a specific capacitance of 116 F g-1at 0.02 A g-1, optimal rate capability (76 F g-1at 10 A g-1), and electrochemical stability during galvanostatic charge/discharge cycling and folding/bending stresses.

Involved external institutions

Italian Institute of Technology / Istituto Italiano di Tecnologia (IIT) IT Italy (IT) BeDimensional IT Italy (IT) University of Genova / Università degli Studi di Genova IT Italy (IT) University of Chemistry and Technology (UCT) / Vysoká škola chemicko-technologická (VŠCHT) CZ Czech Republic (CZ) Technische Universität Dresden DE Germany (DE)

How to cite

APA:

Bagheri, A., Bellani, S., Beydaghi, H., Eredia, M., Najafi, L., Bianca, G.,... Bonaccorso, F. (2022). Functionalized Metallic 2D Transition Metal Dichalcogenide-Based Solid-State Electrolyte for Flexible All-Solid-State Supercapacitors. ACS nano, 16(10), 16426-16442. https://doi.org/10.1021/acsnano.2c05640

MLA:

Bagheri, Ahmad, et al. "Functionalized Metallic 2D Transition Metal Dichalcogenide-Based Solid-State Electrolyte for Flexible All-Solid-State Supercapacitors." ACS nano 16.10 (2022): 16426-16442.

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