Solid-state NMR insights into alcohol adsorption by metal-organic frameworks: adsorption state, selectivity, and adsorption-induced phase transitions

Khan AH, Salout SA, Shupletsov L, De A, Senkovska I, Kaskel S, Brunner E (2022)

Publication Type: Journal article

Publication year: 2022

Journal

Chemical Communications Royal Society of Chemistry

Abstract

Alcohol adsorption by metal-organic frameworks (ZIF-8 and ZIF-11) in aqueous solutions is investigated including alcohol mixtures. Solid-state ¹³C NMR spectroscopy is demonstrated to be well-suited for such liquid-phase adsorption studies at the molecular level. Adsorption-induced immobilization could be visualized. Finally, an unexpected phase transition of ZIF-11 was discovered.

Involved external institutions

Technische Universität Dresden

Germany (DE)

How to cite

APA:

Khan, A.H., Salout, S.A., Shupletsov, L., De, A., Senkovska, I., Kaskel, S., & Brunner, E. (2022). Solid-state NMR insights into alcohol adsorption by metal-organic frameworks: adsorption state, selectivity, and adsorption-induced phase transitions. Chemical Communications. https://doi.org/10.1039/d2cc00638c

MLA:

Khan, Arafat Hossain, et al. "Solid-state NMR insights into alcohol adsorption by metal-organic frameworks: adsorption state, selectivity, and adsorption-induced phase transitions." Chemical Communications (2022).

BibTeX: Download