Single particle Raman spectroscopy analysis of the metal-organic framework DUT-8(Ni) switching transition under hydrostatic pressure
Krylov A, Senkovska I, Ehrling S, Maliuta M, Krylova S, Slyusareva E, Vtyurin A, Kaskel S (2020)
Publication Type: Journal article
Publication year: 2020
Journal
Book Volume: 56
Pages Range: 8269-8272
Journal Issue: 59
DOI: 10.1039/d0cc02491k
Abstract
Experimental in situ observations of phase coexistence in switchable metal-organic frameworks are reported to provide a fundamental understanding of dynamic adsorbents that can change their pore structure in response to external stimuli. A prototypical flexible pillared layer framework DUT-8(Ni) (DUT = Dresden University of Technology) was studied under hydrostatic pressure by in situ Raman spectroscopy on single crystals. The closing transition of the open pore phase (op) containing DMF in the pores in silicon oil as a pressure transmitting fluid, as well as the closed pore phase (cp) to op transition under pressure in methanol, were studied. Phase coexistences during both transitions were observed. This journal is
Involved external institutions
Federal Research Center "Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences"
Russian Federation (RU)
Technische Universität Dresden
Germany (DE)
Siberian Federal University (SibFU) / Сибирский федеральный университет
Russian Federation (RU)
Russian Federation (RU)
Technische Universität Dresden
Germany (DE)
Siberian Federal University (SibFU) / Сибирский федеральный университет
Russian Federation (RU)
How to cite
APA:
Krylov, A., Senkovska, I., Ehrling, S., Maliuta, M., Krylova, S., Slyusareva, E.,... Kaskel, S. (2020). Single particle Raman spectroscopy analysis of the metal-organic framework DUT-8(Ni) switching transition under hydrostatic pressure. Chemical Communications, 56(59), 8269-8272. https://doi.org/10.1039/d0cc02491k
MLA:
Krylov, Alexander, et al. "Single particle Raman spectroscopy analysis of the metal-organic framework DUT-8(Ni) switching transition under hydrostatic pressure." Chemical Communications 56.59 (2020): 8269-8272.
BibTeX: Download