Interfacing porphyrins and carbon nanotubes through mechanical links
De Juan-Fernandez L, Münich PW, Puthiyedath A, Nieto-Ortega B, Casado S, Ruiz-Gonzalez L, Perez EM, Guldi DM (2018)
Publication Type: Journal article
Publication year: 2018
Journal
Book Volume: 9
Pages Range: 6779-6784
Journal Issue: 33
DOI: 10.1039/c8sc02492h
Abstract
We describe the synthesis of rotaxane-type species composed of macrocyclic porphyrin rings mechanically interlocked with SWCNT threads. The formation of mechanically interlocked SWCNTs (MINTs) proceeds with chiral selectivity, and was confirmed by spectroscopic and analytical techniques and adequate control experiments, and corroborated by high-resolution electron microscopy. From a thorough characterization of the MINTs through UV-vis-NIR absorption, fluorescence, Raman, and transient absorption spectroscopy we analyse in detail the electronic interactions of the porphyrins and the SWCNTs in the ground and excited states.
Authors with CRIS profile
Peter Wilhelm Münich
Lehrstuhl für Physikalische Chemie I
Arjun Menon
Sonderforschungsbereich 953/3 Synthetische Kohlenstoffallotrope
Dirk Michael Guldi
Lehrstuhl für Physikalische Chemie I
Involved external institutions
Spain (ES)How to cite
APA:
De Juan-Fernandez, L., Münich, P.W., Puthiyedath, A., Nieto-Ortega, B., Casado, S., Ruiz-Gonzalez, L.,... Guldi, D.M. (2018). Interfacing porphyrins and carbon nanotubes through mechanical links. Chemical Science, 9(33), 6779-6784. https://doi.org/10.1039/c8sc02492h
MLA:
De Juan-Fernandez, Leire, et al. "Interfacing porphyrins and carbon nanotubes through mechanical links." Chemical Science 9.33 (2018): 6779-6784.
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