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Osmium and lithium isotope evidence for weathering feedbacks linked to orbitally paced organic carbon burial and Silurian glaciations

Sproson AD, Pogge von Strandmann PA, Selby D, Jarochowska E, Frýda J, Hladil J, Loydell DK, Slavík L, Calner M, Maier G, Munnecke A, Lenton TM (2022)

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Publication Type: Journal article

Publication year: 2022

Journal

Book Volume: 577

Article Number: 117260

DOI: 10.1016/j.epsl.2021.117260

Abstract

The Ordovician (∼487 to 443 Ma) ended with the formation of extensive Southern Hemisphere ice sheets, known as the Hirnantian glaciation, and the second largest mass extinction in Earth History. It was followed by the Silurian (∼443 to 419 Ma), one of the most climatically unstable periods of the Phanerozoic as evidenced by several large scale (>5‰) carbon isotope (δ¹³C) perturbations associated with further extinction events. Despite several decades of research, the cause of these environmental instabilities remains enigmatic. Here, we provide osmium (¹⁸⁷Os/¹⁸⁸Os) and lithium (δ⁷Li) isotope measurements of marine sedimentary rocks that cover four Silurian δ¹³C excursions. Osmium and Li isotope records resemble those previously recorded for the Hirnantian glaciation suggesting a similar causal mechanism. When combined with a new dynamic carbon-osmium-lithium biogeochemical model we suggest that astronomical forcing of the marine organic carbon cycle, as opposed to a decline in volcanic arc degassing or the rise of early land plants, resulted in drawdown of atmospheric CO2, triggering continental scale glaciation, intense global cooling and eustatic sea-level lows recognised in the geological record. Lower atmospheric pCO2 and temperatures during the Hirnantian and Silurian glaciations suppressed CO2 removal by silicate weathering, driving ¹⁸⁷Os/¹⁸⁸Os and δ⁷Li variability, supporting the existence of climate-regulating feedbacks.

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APA:

Sproson, A.D., Pogge von Strandmann, P.A., Selby, D., Jarochowska, E., Frýda, J., Hladil, J.,... Lenton, T.M. (2022). Osmium and lithium isotope evidence for weathering feedbacks linked to orbitally paced organic carbon burial and Silurian glaciations. Earth and Planetary Science Letters, 577. https://doi.org/10.1016/j.epsl.2021.117260

MLA:

Sproson, Adam D., et al. "Osmium and lithium isotope evidence for weathering feedbacks linked to orbitally paced organic carbon burial and Silurian glaciations." Earth and Planetary Science Letters 577 (2022).

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