Thermochemical and Structural Studies of New Chiral and Achiral Long Alkyl Chain Functionalized Imidazolinium Ionic Liquids

Seidl V, Sternberg M, Heinemann FW, Schmiele M, Unruh T, Wasserscheid P, Meyer K (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Crystal Growth and Design American Chemical Society

DOI: 10.1021/acs.cgd.1c00734

Abstract

Adding to the versatile class of ionic liquids (ILs), an entirely new series of imidazolinium-based ionic liquids is reported herein, offering chirality and important thermal characteristics, such as polymorphism, glass transition, and plastic crystalline behavior. An efficient and general procedure for the preparation of long N,N′-alkyl chain-substituted compounds with either saturated (s) or chiral (c) cyclohexyl (cyC6)-substituted imidazolium (Im) backbones, namely, [C12C12RsIm][A] (A = Br-, [BF4]-, [ClO4]-, [PF6]- R = H, Me, iPr) and [C12C12cIm-cyC6][A] (A = Br-, I-, [I3]-, [BF4]-, [ClO4]-, [PF6]-, [SbF6]-, [BPh4]-), was developed, and the novel compounds were studied by thermochemical methods (DSC, TGA), X-ray diffraction in the small angle regime (SAXS), single-crystal X-ray diffraction (SC-XRD), and specific rotation analysis.

Authors with CRIS profile

Vera Seidl Lehrstuhl für Anorganische und Allgemeine Chemie Michelle Sternberg Lehrstuhl für Anorganische und Allgemeine Chemie Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Martin Schmiele Professur für Nanomaterialcharakterisierung (Streumethoden) Tobias Unruh Professur für Nanomaterialcharakterisierung (Streumethoden) Peter Wasserscheid Lehrstuhl für Chemische Reaktionstechnik (CRT) Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

How to cite

APA:

Seidl, V., Sternberg, M., Heinemann, F.W., Schmiele, M., Unruh, T., Wasserscheid, P., & Meyer, K. (2021). Thermochemical and Structural Studies of New Chiral and Achiral Long Alkyl Chain Functionalized Imidazolinium Ionic Liquids. Crystal Growth and Design. https://doi.org/10.1021/acs.cgd.1c00734

MLA:

Seidl, Vera, et al. "Thermochemical and Structural Studies of New Chiral and Achiral Long Alkyl Chain Functionalized Imidazolinium Ionic Liquids." Crystal Growth and Design (2021).

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