Abrasive blasting of lithium metal surfaces yields clean and 3D structured lithium metal anodes with superior properties

Wolf A, Lorrmann H, Flegler A, Wolf AJ, Guerfi A, Mandel K, Giffin GA (2021)

Publication Type: Journal article, Original article

Publication year: 2021

Journal

Energy Technology Wiley-Blackwell

Original Authors: Andreas Wolf, Henning Lorrmann, Andreas Flegler, Andreas Wolf, Abdelbast Guerfi, Karl Mandel, Guinevere A. Giffin

Article Number: ente.202100455

DOI: 10.1002/ente.202100455

Abstract

Avoiding harmful passivation of the lithium metal surface during its implementation as an anode material is a challenge to its use in rechargeable lithium metal batteries. It is critical to control the chemical composition and the morphology of the native passivation layer and to avoid contamination by lubricants or other substances involved in the processing. Herein, abrasive blasting is used as a physical method to achieve clean and 3D-structured lithium metal electrodes. The careful choice of the abrasive agent and the blasting parameters results in well-controlled surface properties. The blasted lithium electrodes exhibit significantly lower overvoltages with values as low as 10 mV at 0.1 mA cm−2. Electrochemical impedance spectroscopy shows that blasted lithium has interface resistances that are up to five times smaller than those of untreated lithium. The effectiveness of blasting as a cleaning method is clear even in the case of thicker and highly resistive passivation layers occurring after exposure to ambient air.

Authors with CRIS profile

Andreas Wolf Professur für Anorganische Chemie Karl Mandel Professur für Anorganische Chemie

Involved external institutions

Fraunhofer Institut für Silicatforschung (ISC) DE Germany (DE) Hydro-Québec CA Canada (CA)

How to cite

APA:

Wolf, A., Lorrmann, H., Flegler, A., Wolf, A.J., Guerfi, A., Mandel, K., & Giffin, G.A. (2021). Abrasive blasting of lithium metal surfaces yields clean and 3D structured lithium metal anodes with superior properties. Energy Technology. https://doi.org/10.1002/ente.202100455

MLA:

Wolf, Andreas, et al. "Abrasive blasting of lithium metal surfaces yields clean and 3D structured lithium metal anodes with superior properties." Energy Technology (2021).

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