Reactivity and Passivation of Fe Nanoclusters on h-BN/Rh(111)

Waleska N, Düll F, Bachmann P, Hemauer F, Steinhauer J, Papp C (2021)

Publication Type: Journal article

Publication year: 2021

Journal

DOI: 10.1002/chem.202102590

Abstract

The reactivity of iron nanocluster arrays on h-BN/Rh(111) was studied using in situ high-resolution X-ray photoelectron spectroscopy. The morphology and reactivity of the iron nanoclusters (Fe-NCs) were investigated by CO adsorption. On-top and hollow/edge sites were determined to be the available adsorption sites on the as-prepared Fe-NCs and CO dissociation was observed at 300 K. C- and O-precovered Fe-NCs showed no catalytic activity towards CO dissociation because the hollow/edge sites were blocked by the C and O atoms. Therefore, these adsorption sites were identified to be the most active sites of the Fe-NCs.

Authors with CRIS profile

Natalie Waleska-Wellnhofer Naturwissenschaftliche Fakultät Fabian Düll Lehrstuhl für Physikalische Chemie II Philipp Bachmann Lehrstuhl für Physikalische Chemie II Felix Hemauer Lehrstuhl für Physikalische Chemie II Johann Steinhauer Lehrstuhl für Physikalische Chemie II Christian Papp Lehrstuhl für Physikalische Chemie II

How to cite

APA:

Waleska, N., Düll, F., Bachmann, P., Hemauer, F., Steinhauer, J., & Papp, C. (2021). Reactivity and Passivation of Fe Nanoclusters on h-BN/Rh(111). Chemistry - A European Journal. https://doi.org/10.1002/chem.202102590

MLA:

Waleska, Natalie, et al. "Reactivity and Passivation of Fe Nanoclusters on h-BN/Rh(111)." Chemistry - A European Journal (2021).

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