Immobilized Ru-Pincer Complexes for Continuous Gas-Phase Low-Temperature Methanol Reforming-Improving the Activity by a Second Ru-Complex and Variation of Hydroxide Additives
Schwarz C, Kraus D, Alberico E, Junge H, Haumann M (2021)
Publication Type: Journal article
Publication year: 2021
Journal
Abstract
Ru-pincer complexes were immobilized as supported liquid phase (SLP) materials to allow the methanol reforming reaction as continuous gas phase process. Under reaction conditions, the liquid phase forms from the hydroxide coating. Several hydroxides were screened and CsOH showed highest activity compared to the standard KOH coating. The well-known Ru-pincer complex carbonylchlorohydrido [bis(2-di-i-propylphosphinoethyl)amine]ruthenium(II) is limited in catalyzing the final step of the methanol reforming. Addition of a second complex, having a methylated backbone in the pincer-ligand, could overcome these limitations. Significant enhancement of the overall catalytic activity was observed.
Authors with CRIS profile
Christian Schwarz
Lehrstuhl für Chemische Reaktionstechnik (CRT)
Dominik Kraus
Lehrstuhl für Chemische Reaktionstechnik (CRT)
Marco Haumann
Lehrstuhl für Chemische Reaktionstechnik (CRT)
Involved external institutions
Germany (DE)How to cite
APA:
Schwarz, C., Kraus, D., Alberico, E., Junge, H., & Haumann, M. (2021). Immobilized Ru-Pincer Complexes for Continuous Gas-Phase Low-Temperature Methanol Reforming-Improving the Activity by a Second Ru-Complex and Variation of Hydroxide Additives. European Journal of Inorganic Chemistry. https://doi.org/10.1002/ejic.202100042
MLA:
Schwarz, Christian, et al. "Immobilized Ru-Pincer Complexes for Continuous Gas-Phase Low-Temperature Methanol Reforming-Improving the Activity by a Second Ru-Complex and Variation of Hydroxide Additives." European Journal of Inorganic Chemistry (2021).
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