Structural, electronic, and vibrational properties of (4,4) picotube crystals

Machon M, Reich S, Maultzsch J, Okudera H, Simon A, Herges R, Thomsen C (2005)

Publication Status: Published

Publication Type: Journal article

Publication year: 2005

Journal

Physical Review B American Physical Society

Publisher: AMER PHYSICAL SOC

Book Volume: 72

Journal Issue: 15

DOI: 10.1103/PhysRevB.72.155402

Abstract

The picotube molecule is a highly symmetric hydrocarbon, closely related to a very short (4,4) carbon nanotube. We present a thorough experimental and theoretical study of the physical properties of picotube crystals. In x-ray diffraction experiments we find the picotube molecules to display D-2d symmetry. We identify the most intense Raman peaks as A(1) modes with polarization-dependent Raman measurements. Ab initio calculations of the structural, electronic, and vibrational properties of picotubes are in excellent agreement with our experiments. We assign the measured vibrations to displacement eigenvectors including those analogous to the nanotube high-energy mode, the D mode, and the radial-breathing mode.

Authors with CRIS profile

Janina Maultzsch Lehrstuhl für Experimentalphysik

Involved external institutions

Technische Universität Berlin DE Germany (DE) Freie Universität Berlin DE Germany (DE) Christian-Albrechts-Universität zu Kiel DE Germany (DE) Max-Planck-Institut für Festkörperforschung DE Germany (DE)

How to cite

APA:

Machon, M., Reich, S., Maultzsch, J., Okudera, H., Simon, A., Herges, R., & Thomsen, C. (2005). Structural, electronic, and vibrational properties of (4,4) picotube crystals. Physical Review B, 72(15). https://doi.org/10.1103/PhysRevB.72.155402

MLA:

Machon, Maria, et al. "Structural, electronic, and vibrational properties of (4,4) picotube crystals." Physical Review B 72.15 (2005).

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