Two Rings Around One Ball: Stability and Charge Localization of [1 : 1] and [2 : 1] Complex Ions of [10]CPP and C60/70[*]

Freiberger M, Minameyer M, Solymosi I, Frühwald S, Krug M, Xu Y, Hirsch A, Clark T, Guldi DM, von Delius M, Amsharov K, Görling A, Perez-Ojeda Rodriguez ME, Drewello T (2022)

Publication Type: Journal article

Publication year: 2022

Journal

Book Volume: 29

Article Number: e202203734

Journal Issue: 16

DOI: 10.1002/chem.202203734

Abstract

We investigate the gas-phase chemistry of noncovalent complexes of [10]cycloparaphenylene ([10]CPP) with C60 and C70 by means of atmospheric pressure photoionization and electrospray ionization mass spectrometry. The literature-known [1 : 1] complexes, namely [10]CPP⊃C60 and [10]CPP⊃C70, are observed as radical cations and anions. Their stability and charge distribution are studied using energy-resolved collision-induced dissociation (ER-CID). These measurements reveal that complexes with a C70 core exhibit a greater stability and, on the other hand, that the radical cations are more stable than the respective radical anions. Regarding the charge distribution, in anionic complexes charges are exclusively located on C60 or C70, while the charges reside on [10]CPP in the case of cationic complexes. [2 : 1] complexes of the ([10]CPP2⊃C60/70)⁺⋅^/−⋅ type are observed for the first time as isolated solitary gas-phase species. Here, C60-based [2 : 1] complexes are less stable than the respective C70 analogues. By virtue of the high stability of cationic [1 : 1] complexes, [2 : 1] complexes show a strongly reduced stability of the radical cations. DFT analyses of the minimum geometries as well as molecular dynamics calculations support the experimental data. Furthermore, our novel gas-phase [2 : 1] complexes are also found in 1,2-dichlorobenzene. Insights into the thermodynamic parameters of the binding process as well as the species distribution are derived from isothermal titration calorimetry (ITC) measurements.

Authors with CRIS profile

Involved external institutions

Universität Ulm Germany (DE) Martin-Luther-Universität Halle-Wittenberg (MLU) Germany (DE)

How to cite

APA:

Freiberger, M., Minameyer, M., Solymosi, I., Frühwald, S., Krug, M., Xu, Y.,... Drewello, T. (2022). Two Rings Around One Ball: Stability and Charge Localization of [1 : 1] and [2 : 1] Complex Ions of [10]CPP and C60/70[*]. Chemistry - A European Journal, 29(16). https://doi.org/10.1002/chem.202203734

MLA:

Freiberger, Markus, et al. "Two Rings Around One Ball: Stability and Charge Localization of [1 : 1] and [2 : 1] Complex Ions of [10]CPP and C60/70[*]." Chemistry - A European Journal 29.16 (2022).

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