Carrier Transport and Recombination in Efficient "All-Small-Molecule" Solar Cells with the Nonfullerene Acceptor IDTBR

Liang R, Babics M, Savikhin V, Zhang W, Le Corre VM, Lopatin S, Kan Z, Firdaus Y, Liu S, Mcculloch I, Toney MF, Beaujuge PM (2018)

Publication Status: Published

Publication Type: Journal article

Publication year: 2018

Journal

Advanced Energy Materials Wiley

Publisher: WILEY-V C H VERLAG GMBH

Book Volume: 8

Article Number: ARTN 1800264

Journal Issue: 19

DOI: 10.1002/aenm.201800264

Abstract

Reaching device efficiencies that can rival those of polymer-fullerene Bulk Heterojunction (BHJ) solar cells (>10%) remains challenging with the ''All-Small-Molecule'' (All-SM) approach, in part because of (i) the morphological limitations that prevail in the absence of polymer and (ii) the difficulty to raise and balance out carrier mobilities across the active layer. In this report, the authors show that blends of the SM donor DR3TBDTT (DR3) and the nonfullerene SM acceptor O-IDTBR are conducive to ''All-SM'' BHJ solar cells with high open-circuit voltages (V-OC) >1.1 V and PCEs as high as 6.4% (avg. 6.1%) when the active layers are subjected to a post-processing solvent vapor-annealing (SVA) step with dimethyl disulfide (DMDS). Combining electron energy loss spectroscopy (EELS) analyses and systematic carrier recombination examinations, the authors show that SVA treatments with DMDS play a determining role in improving charge transport and reducing non-geminate recombination for the DR3:O-IDTBR system. Correlating the experimental results and device simulations, it is found that substantially higher BHJ solar cell efficiencies of >12% can be achieved if the IQE and carrier mobilities of the active layer are increased to >85% and >10(-4) cm(2) V-1 s(-1), respectively, while suppressing the recombination rate constant k to <10(-12) cm(3) s(-1).

Authors with CRIS profile

Vincent Marc Le Corre Institute Materials for Electronics and Energy Technology (i-MEET)

Involved external institutions

King Abdullah University of Science and Technology (KAUST) / جامعة الملك عبد الله للعلوم و التقنية SA Saudi Arabia (SA) Stanford National Accelerator Laboratory (SLAC) US United States (USA) (US)

How to cite

APA:

Liang, R., Babics, M., Savikhin, V., Zhang, W., Le Corre, V.M., Lopatin, S.,... Beaujuge, P.M. (2018). Carrier Transport and Recombination in Efficient "All-Small-Molecule" Solar Cells with the Nonfullerene Acceptor IDTBR. Advanced Energy Materials, 8(19). https://dx.doi.org/10.1002/aenm.201800264

MLA:

Liang, Ru‐Ze, et al. "Carrier Transport and Recombination in Efficient "All-Small-Molecule" Solar Cells with the Nonfullerene Acceptor IDTBR." Advanced Energy Materials 8.19 (2018).

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