Sulfoxide hemithioindigo tweezers - visible light addressable capture and release
Bartelmann T, Gnannt F, Zitzmann M, Mayer P, Dube H (2021)
Publication Type: Journal article
Publication year: 2021
Journal
Book Volume: 12
Pages Range: 3651-3659
Journal Issue: 10
DOI: 10.1039/d0sc04981f
Abstract
Introducing responsive elements into supramolecular recognition systems offers great advantages for the control of intermolecular interactions and represents an important stepping stone towards multi-purpose and reprogrammable synthetic systems. Of particular interest is implementation of light-responsiveness because of the unique ease and precision of this signal. Here we present visible light responsive hemithioindigo-based molecular tweezers that bear a highly polar sulfoxide function as an additional recognition unit inside their binding site. Sulfur oxidation allows to simultaneously enhance all crucial properties of this receptor typei.e.photoswitching capability, thermal stability of individual switching states, binding affinity, and binding modulation upon switching. With a novel titration method the thermodynamic binding parameters were determined using reduced sample amounts. Employing these strongly enhanced molecular tweezers allowed to demonstrate photocontrol of intermolecular charge transfer in a reversible manner.
Authors with CRIS profile
Frederik Gnannt
Lehrstuhl für Organische Chemie I
Max Zitzmann
Lehrstuhl für Organische Chemie I
Henry Dube
Lehrstuhl für Organische Chemie I
Involved external institutions
Germany (DE)How to cite
APA:
Bartelmann, T., Gnannt, F., Zitzmann, M., Mayer, P., & Dube, H. (2021). Sulfoxide hemithioindigo tweezers - visible light addressable capture and release. Chemical Science, 12(10), 3651-3659. https://doi.org/10.1039/d0sc04981f
MLA:
Bartelmann, Thomas, et al. "Sulfoxide hemithioindigo tweezers - visible light addressable capture and release." Chemical Science 12.10 (2021): 3651-3659.
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