Expanding the scope of biogenic substrates for the selective production of formic acid from water-insoluble and wet waste biomass

Beitrag in einer Fachzeitschrift


Details zur Publikation

Autor(en): Albert J, Wasserscheid P
Zeitschrift: Green Chemistry
Verlag: Royal Society of Chemistry
Jahr der Veröffentlichung: 2015
ISSN: 1463-9262
eISSN: 1463-9270
Sprache: Englisch


Abstract


The selective oxidation of complex, water-insoluble and wet biomasses from second and third generation to formic acid including effective catalyst recycling is reported. Additionally, the relevance and limits of potential contaminants are illustrated by different experimental approaches. By using a very robust homogeneous polyoxometalate catalyst in aqueous solution, molecular oxygen as oxidant and an acid as solubilizer, it is possible to convert different lignocellulosic and algae feedstock into formic acid and pure carbon dioxide. The applied green oxidation system benefits from its low reaction temperature (below 100 °C) and its very selective nature. Furthermore, catalyst recycling over three batches has been successfully carried out.


FAU-Autoren / FAU-Herausgeber

Albert, Jakob Dr.-Ing.
Lehrstuhl für Chemische Reaktionstechnik
Wasserscheid, Peter Prof. Dr.
Lehrstuhl für Chemische Reaktionstechnik


Zitierweisen

APA:
Albert, J., & Wasserscheid, P. (2015). Expanding the scope of biogenic substrates for the selective production of formic acid from water-insoluble and wet waste biomass. Green Chemistry. https://dx.doi.org/10.1039/C5GC01474C

MLA:
Albert, Jakob, and Peter Wasserscheid. "Expanding the scope of biogenic substrates for the selective production of formic acid from water-insoluble and wet waste biomass." Green Chemistry (2015).

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Zuletzt aktualisiert 2018-17-10 um 01:20