Model-Based Identification and Experimental Validation of the Optimal Reaction Route for the Hydroformylation of 1-Dodecene
Beitrag in einer Fachzeitschrift
Details zur Publikation
Autor(en): Hentschel B, Kiedorf G, Gerlach M, Hamel C, Seide-Morgenstern A, Freund H, Sundmacher K
Zeitschrift: → Industrial & Engineering Chemistry Research |
Verlag: ACS American Chemical Society
Jahr der Veröffentlichung: 2015
Band: 54
Heftnummer: 6
Seitenbereich: 1755-1765
ISSN: 0888-5885
Abstract
Previously developed kinetic and dynamic models of the hydroformylation of 1-dodecene in a thermomorphic multicomponent solvent system (TMS), consisting of DMF, n-decane, and hydroformylation products, were experimentally validated applying various operation modes, such as batch, semibatch, and perturbed batch operation. On the basis of experimentally obtained data, which cover a broad range of physical conditions, the parameters of the reaction kinetics were refined to give reliable model predictions as basis for rigorous process optimization. The improved model was used for dynamic optimization to obtain optimal trajectories (e.g., temperature and gas dosing fluxes versus reaction time), which maximize the selectivity to the desired linear aldehyde product. The predicted optimal trajectories were successfully validated in semibatch reactor experiments.
FAU-Autoren / FAU-Herausgeber
| Freund, Hannsjörg Prof. Dr. |
| | Professur für Katalytische Reaktoren und Prozesstechnik |
|
Autor(en) der externen Einrichtung(en)
→ Max-Planck-Institut für Dynamik komplexer technischer Systeme / Max Planck Institute for Dynamics of Complex Technical Systems |
→ Otto-von-Guericke-Universität Magdeburg |
Zitierweisen
APA: | Hentschel, B., Kiedorf, G., Gerlach, M., Hamel, C., Seide-Morgenstern, A., Freund, H., & Sundmacher, K. (2015). Model-Based Identification and Experimental Validation of the Optimal Reaction Route for the Hydroformylation of 1-Dodecene. Industrial & Engineering Chemistry Research, 54(6), 1755-1765. https://dx.doi.org/10.1021/ie504388t |
MLA: | Hentschel, Benjamin, et al. "Model-Based Identification and Experimental Validation of the Optimal Reaction Route for the Hydroformylation of 1-Dodecene." Industrial & Engineering Chemistry Research 54.6 (2015): 1755-1765. |