Otte M, Kuijpers PF, Tröppner O, Ivanovic-Burmazovic I, Reek JN, de Bruin B (2014)
Publication Type: Journal article, Original article
Publication year: 2014
Original Authors: Otte M., Kuijpers P.F., Troeppner O., Ivanovic-Burmazovic I., Reek J.N.H., De Bruin B.
Publisher: Wiley-VCH Verlag
Book Volume: 20
Pages Range: 4880-4884
Journal Issue: 17
A cobalt-porphyrin catalyst encapsulated in a cubic ML cage allows cyclopropanation reactions in aqueous media. The caged-catalyst shows enhanced activities in acetone/water as compared to pure acetone. Interestingly, the ML encapsulated catalyst reveals size-selectivity. Smaller substrates more easily penetrate through the pores of the "molecular ship-in-a-bottle catalysts" and are hence converted faster than bigger substrates. In addition, N-tosylhydrazone sodium salts are easy to handle reagents for cyclopropanation reactions under these conditions. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
APA:
Otte, M., Kuijpers, P.F., Tröppner, O., Ivanovic-Burmazovic, I., Reek, J.N., & de Bruin, B. (2014). Encapsulated cobalt-porphyrin as a catalyst for size-selective radical-type cyclopropanation reactions. Chemistry - A European Journal, 20(17), 4880-4884. https://doi.org/10.1002/chem.201400055
MLA:
Otte, Matthias, et al. "Encapsulated cobalt-porphyrin as a catalyst for size-selective radical-type cyclopropanation reactions." Chemistry - A European Journal 20.17 (2014): 4880-4884.
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