Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on bridging azido ligands

Krause J, Alexandropoulos DI, Carrella LM, Rentschler E, Stamatatos TC (2018)

Publication Type: Journal article

Publication year: 2018

Journal

Chemical Communications Royal Society of Chemistry

Book Volume: 54

Pages Range: 12499-12502

Journal Issue: 88

DOI: 10.1039/c8cc07722c

Abstract

The synthesis of a new family of ferromagnetically-coupled {Ni10} clusters counterbalanced by various [Ln(NO3)5]2- ions is herein described. The resulting compounds are organic chelate-free and the metal ions are exclusively bridged by end-on azido ligands to stabilize a beautiful disk-like topology reminiscent of the structure of the brucite mineral.

Involved external institutions

Johannes Gutenberg-Universität Mainz (JGU) DE Germany (DE) Brock University CA Canada (CA)

How to cite

APA:

Krause, J., Alexandropoulos, D.I., Carrella, L.M., Rentschler, E., & Stamatatos, T.C. (2018). Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on bridging azido ligands. Chemical Communications, 54(88), 12499-12502. https://doi.org/10.1039/c8cc07722c

MLA:

Krause, Jasmin, et al. "Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on bridging azido ligands." Chemical Communications 54.88 (2018): 12499-12502.

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