Carbon-rich cyclopentadienyl ruthenium allenylidene complexes

Journal article
(Original article)


Publication Details

Author(s): Spörler S, Strinitz F, Rodehutskors P, Müller L, Waterloo A, Dürr M, Hübner E, Ivanovic-Burmazovic I, Tykwinski R, Burzlaff N
Journal: New Journal of Chemistry
Publication year: 2016
Volume: 40
Journal issue: 7
Pages range: 6127-6134
ISSN: 1369-9261


Abstract


Ruthenium allenylidene complexes with carbon-rich polyaromatic moieties have been synthesized by using [RuCl(η-CH)(PPh)] (η-CH = cyclopentadienyl) as a precursor and the propargyl alcohols 10-ethynyl-10-hydroxyanthracen-9-one (ACO), 13-ethynyl-13-hydroxypentacen-6-one (PCO), 1-phenyl-1-(pyren-1-yl)prop-2-yn-1-ol (PyrPh), 9-ethynyl-9H-fluoren-9-ol (FN) and 6-ethynyl-6H-benzo[cd]pyren-6-ol (BPyr) as ligands. The resulting cationic allenylidene complexes, [Ru(η-CH)(CC(AO))(PPh)]PF (1), [Ru(η-CH)(CC(PCO))(PPh)]PF (2), [Ru(η-CH)(CC(PyrPh))(PPh)]PF (3), [Ru(η-CH)(CC(FN))(PPh)]PF (4), and [Ru(η-CH)(CC(BPyr))(PPh)]PF (5) show interesting intermolecular π-interactions in the solid-state structure as well as solution state complexation with pyrene (documented by Job's plots experiments). CV data indicate possible Ru(ii)/Ru(iii) oxidation, as well as the potential reduction of the carbon-rich allenylidene moiety.



FAU Authors / FAU Editors

Burzlaff, Nicolai Prof. Dr.
Professur für Anorganische Chemie
Dürr, Maximilian
Lehrstuhl für Bioanorganische Chemie
Ivanovic-Burmazovic, Ivana Prof. Dr.
Lehrstuhl für Bioanorganische Chemie
Müller, Lisa
Professur für Anorganische Chemie
Rodehutskors, Philipp
Professur für Anorganische Chemie
Spörler, Susanne
Professur für Anorganische Chemie
Strinitz, Frank
Professur für Anorganische Chemie
Waterloo, Andreas
Lehrstuhl für Organische Chemie I


How to cite

APA:
Spörler, S., Strinitz, F., Rodehutskors, P., Müller, L., Waterloo, A., Dürr, M.,... Burzlaff, N. (2016). Carbon-rich cyclopentadienyl ruthenium allenylidene complexes. New Journal of Chemistry, 40(7), 6127-6134. https://dx.doi.org/10.1039/c5nj03556b

MLA:
Spörler, Susanne, et al. "Carbon-rich cyclopentadienyl ruthenium allenylidene complexes." New Journal of Chemistry 40.7 (2016): 6127-6134.

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Last updated on 2018-19-04 at 03:33