Excited State Dynamics of Odd [n]Cumulenes: Chain Length and Conformational Effects

Ullrich T, Sun B, Yang Y, Schüßlbauer C, Ferguson MJ, Fazzi D, Negri F, Tommasini M, Tykwinski RR, Guldi DM (2025)

Publication Type: Journal article

Publication year: 2025

Journal

Journal of the American Chemical Society American Chemical Society

Book Volume: 147

Pages Range: 21419-21431

Journal Issue: 25

DOI: 10.1021/jacs.5c00147

Abstract

Over the past decades, carbon allotropes have been extensively studied and applied to various technological applications due to their unique electronic and optical properties. Contemporary research has focused on quasi-1D, 2D, and 3D materials. On the other hand, the synthesis and isolation of carbyne as the 1D sp-hybridized carbon nanostructure remains elusive. Significant effort has been directed toward synthesis and study of carbon atomic wires (CAWs) as finite analogues of carbyne. The properties of CAWs composed of alkyne building blocks (oligoynes and polyynes) have provided glimpses of the potential properties of carbyne, while the synthesis and study of the alternative structure of CAWs, [n]cumulenes, remains in its infancy. Herein, we present an in-depth photophysical investigation of three odd [n]cumulenes (n = 3, 5, 7) assisted by quantum-chemical calculations. In contrast to the oligoynes, the photophysical properties of cumulenic carbon chains are dramatically impacted by both length and conformational effects of terminal end groups. We demonstrate how the subtle control over rotational motion with respect to the terminal CC bonds of cumulenes alters their electronic ground and excited states as well as dominating the photophysical deactivation cascade.

Authors with CRIS profile

Tobias Ullrich Lehrstuhl für Physikalische Chemie I Christoph Schüßlbauer Lehrstuhl für Physikalische Chemie I Dirk Michael Guldi Lehrstuhl für Physikalische Chemie I

Involved external institutions

University of Alberta CA Canada (CA) University of Bologna / Università di Bologna IT Italy (IT) Politecnico di Milano IT Italy (IT)

How to cite

APA:

Ullrich, T., Sun, B., Yang, Y., Schüßlbauer, C., Ferguson, M.J., Fazzi, D.,... Guldi, D.M. (2025). Excited State Dynamics of Odd [n]Cumulenes: Chain Length and Conformational Effects. Journal of the American Chemical Society, 147(25), 21419-21431. https://doi.org/10.1021/jacs.5c00147

MLA:

Ullrich, Tobias, et al. "Excited State Dynamics of Odd [n]Cumulenes: Chain Length and Conformational Effects." Journal of the American Chemical Society 147.25 (2025): 21419-21431.

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