Nonlinear optovibronics in molecular systems
Zhang Q, Asjad M, Reitz M, Sommer C, Gurlek B, Genes C (2024)
Publication Type: Journal article
Publication year: 2024
Journal
Book Volume: 109
Article Number: 023714
Journal Issue: 2
DOI: 10.1103/PhysRevA.109.023714
Abstract
We analytically tackle optovibronic interactions in molecular systems driven by either classical or quantum light fields. In particular, we examine a simple model of molecules with two relevant electronic levels, characterized by potential landscapes with different positions of minima along the internuclear coordinates and of varying curvatures. Such systems exhibit an electron-vibron interaction, which can be composed of linear and quadratic terms in the vibrational displacement. By employing a combination of conditional displacement and squeezing operators, we present analytical expressions based on a quantum Langevin equations approach, to describe the emission and absorption spectra of such nonlinear molecular systems. Furthermore, we examine the imprint of the quadratic interactions onto the transmission properties of a cavity-molecule system within the collective strong-coupling regime of cavity quantum electrodynamics.
Additional Organisation(s)
Involved external institutions
Max-Planck-Institut für die Physik des Lichts (MPL) / Max Planck Institute for the Science of Light
Germany (DE)
Khalifa University of Science, Technology & Research (KUSTAR) / جامعة خليفة
United Arab Emirates (AE)
University of California, San Diego
United States (USA) (US)
Alpine Quantum Technologies
Austria (AT)
Max-Planck-Instituts für Struktur und Dynamik der Materie (MPSD) / Max Planck Institute for the Structure and Dynamics of Matter
Germany (DE)
Germany (DE)
Khalifa University of Science, Technology & Research (KUSTAR) / جامعة خليفة
United Arab Emirates (AE)
University of California, San Diego
United States (USA) (US)
Alpine Quantum Technologies
Austria (AT)
Max-Planck-Instituts für Struktur und Dynamik der Materie (MPSD) / Max Planck Institute for the Structure and Dynamics of Matter
Germany (DE)
How to cite
APA:
Zhang, Q., Asjad, M., Reitz, M., Sommer, C., Gurlek, B., & Genes, C. (2024). Nonlinear optovibronics in molecular systems. Physical Review A, 109(2). https://doi.org/10.1103/PhysRevA.109.023714
MLA:
Zhang, Q., et al. "Nonlinear optovibronics in molecular systems." Physical Review A 109.2 (2024).
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