Low Ti Additions to Stabilize Ru-Ir Electrocatalysts for the Oxygen Evolution Reaction

Lahn L, Mingers AM, Savan A, Ludwig A, Kasian O (2023)

Publication Type: Journal article

Publication year: 2023

Journal

ChemElectroChem Wiley

DOI: 10.1002/celc.202300399

Abstract

Anodic oxygen evolution reaction (OER) challenges large scale application of proton exchange membrane water electrolyzers (PEMWE) due to sluggish kinetics, high overpotential and extremely corrosive environment. While Ir oxides currently provide the best balance between activity and stability, the scarcity of Ir and corresponding high market price lead to poor cost-benefit factors. Mixing Ir with more stable non-precious Ti reduces the noble metal loading and may implicate stabilization, while addition of more catalytically active Ru ensures a high reaction rate. Here, we examine the activity-stability behavior of Ru-Ir-Ti thin film material libraries with low Ti-content under the OER conditions. The high sensitivity to the dissolution of the individual alloy components was achieved by using online and off-line inductively coupled plasma mass spectrometry (ICP-MS) analysis. Our data reveal that even low Ti additions improve the stability of Ru-Ir catalysts without sacrificing activity. In particular, 5 at. % of Ti enable stability increase of Ir in the Ru-Ir catalyst by a factor of 3. Moreover, this catalyst exhibits higher activity compared to the Ti-free Ru-Ir alloys with similar Ir content. Observed activity-stability trends are discussed in light of X-ray photoelectron spectroscopy data.

Authors with CRIS profile

Leopold Lahn Professur für Materialien für die elektrochemische Energiekonversion Olga Kasian Professur für Materialien für die elektrochemische Energiekonversion

Additional Organisation(s)

Institute Materials for Electronics and Energy Technology (i-MEET)

Involved external institutions

Max-Planck-Institut für Eisenforschung GmbH (MPIE) / Max Planck Institute for Iron Research DE Germany (DE) Ruhr-Universität Bochum (RUB) DE Germany (DE)

How to cite

APA:

Lahn, L., Mingers, A.M., Savan, A., Ludwig, A., & Kasian, O. (2023). Low Ti Additions to Stabilize Ru-Ir Electrocatalysts for the Oxygen Evolution Reaction. ChemElectroChem. https://dx.doi.org/10.1002/celc.202300399

MLA:

Lahn, Leopold, et al. "Low Ti Additions to Stabilize Ru-Ir Electrocatalysts for the Oxygen Evolution Reaction." ChemElectroChem (2023).

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