Visible light-mediated catalyst-free radical arylations using arenediazonium salts

Wenisch P, Kuschow M, Heinrich M (2024)


Publication Type: Journal article, Review article

Publication year: 2024

Journal

Book Volume: 2024

Article Number: 202312113

Journal Issue: 2

DOI: 10.24820/ark.5550190.p012.113

Abstract

Radical arylation reactions based on arenediazonium salts have a long history in organic chemistry. While early methods to generate aryl radicals relied on metals, metal catalysts or basic conditions, more recent developments focused on the use of photoredox catalysts. As such catalysts are nevertheless additives, and they thus have to be separated during work-up, an even more attractive option is to exploit charge-transfer complexes between the arenediazonium ion and its substrate to enable aryl radical generation under visible light irradiation. In this review, we summarize recent developments in this particular field of visible light-promoted, additive-free radical arylation reactions.

Authors with CRIS profile

Additional Organisation(s)

How to cite

APA:

Wenisch, P., Kuschow, M., & Heinrich, M. (2024). Visible light-mediated catalyst-free radical arylations using arenediazonium salts. Arkivoc, 2024(2). https://doi.org/10.24820/ark.5550190.p012.113

MLA:

Wenisch, Pia, Meret Kuschow, and Markus Heinrich. "Visible light-mediated catalyst-free radical arylations using arenediazonium salts." Arkivoc 2024.2 (2024).

BibTeX: Download