Molecular Rhodium Complex within N-Rich Porous Polymer Macroligand as Heterogeneous Catalyst for the Visible-Light Driven CO2 Photoreduction
Newar R, Ghosh AC, Kumari Riddhi R, Rajapaksha R, Samanta P, Wisser FM, Canivet J (2023)
Publication Type: Journal article
Publication year: 2023
Journal
Abstract
The heterogenization of molecular catalysts within a porous solid acting as macroligand can advantageously open access to enhanced stability and productivity, and thus to more sustainable catalytic process. Herein, a porous organic polymer (POP) made through metal-free polymerization using bipyridine repeating units is reported. This N-rich POP is an efficient macroligand for the heterogenization of molecular rhodium complexes. The intrinsic catalytic activity of the heterogenized catalyst is slightly higher than that of its homogeneous molecular counterpart for formic acid production as a unique carbon-containing product. The heterogenization of the rhodium catalysts enables recycling for a total productivity of up to 8.3 g of formic acid per gram of catalyst after 7 reuses using visible light as the sole energy source.
Authors with CRIS profile
Florian Wisser
Sonderforschungsbereich 1411 Produktgestaltung disperser Systeme / Design of Particulate Products
Involved external institutions
France (FR)How to cite
APA:
Newar, R., Ghosh, A.C., Kumari Riddhi, R., Rajapaksha, R., Samanta, P., Wisser, F.M., & Canivet, J. (2023). Molecular Rhodium Complex within N-Rich Porous Polymer Macroligand as Heterogeneous Catalyst for the Visible-Light Driven CO2 Photoreduction. Advanced Energy and Sustainability Research. https://dx.doi.org/10.1002/aesr.202300209
MLA:
Newar, Rajashree, et al. "Molecular Rhodium Complex within N-Rich Porous Polymer Macroligand as Heterogeneous Catalyst for the Visible-Light Driven CO2 Photoreduction." Advanced Energy and Sustainability Research (2023).
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