Oefner N, Shuck CE, Schumacher L, Heck F, Hofmann K, Schmidpeter J, Li W, Bahri M, Mehdi BL, Drochner A, Albert B, Hess C, Gogotsi Y, Etzold BJ (2023)
Publication Type: Journal article
Publication year: 2023
Book Volume: 15
Pages Range: 16714-16722
Journal Issue: 13
Selective oxidation reactions are an important class of the current chemical industry and will be highly important for future sustainable chemical production. Especially, the selective oxidation of primary alcohols is expected to be of high future interest, as alcohols can be obtained on technical scales from biomass fermentation. The oxidation of primary alcohols produces aldehydes, which are important intermediates. While selective methanol oxidation is industrially established, the commercial catalyst suffers from deactivation. Ethanol selective oxidation is not commercialized but would give access to sustainable acetaldehyde production when using renewable ethanol. In this work, it is shown that employing 2D MXenes as building blocks allows one to design a nanostructured oxide catalyst composed of mixed valence vanadium oxides, which outperforms on both reactions known materials by nearly an order of magnitude in activity, while showing high selectivity and stability. The study shows that the synthesis route employing 2D materials is key to obtain these attractive catalysts. V
APA:
Oefner, N., Shuck, C.E., Schumacher, L., Heck, F., Hofmann, K., Schmidpeter, J.,... Etzold, B.J. (2023). MXene Aerogel Derived Ultra-Active Vanadia Catalyst for Selective Conversion of Sustainable Alcohols to Base Chemicals. ACS Applied Materials and Interfaces, 15(13), 16714-16722. https://dx.doi.org/10.1021/acsami.2c22720
MLA:
Oefner, Niklas, et al. "MXene Aerogel Derived Ultra-Active Vanadia Catalyst for Selective Conversion of Sustainable Alcohols to Base Chemicals." ACS Applied Materials and Interfaces 15.13 (2023): 16714-16722.
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