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Modulating the Excited-State Decay Pathways of Cu(I) 4 H-Imidazolate Complexes by Excitation Wavelength and Ligand Backbone

Seidler B, Sittig M, Zens C, Tran JH, Müller C, Zhang Y, Schneider KRA, Goerls H, Schubert A, Gräfe S, Schulz M, Dietzek B (2021)

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Publication Type: Journal article

Publication year: 2021

Journal

Book Volume: 125

Pages Range: 11498-11511

Journal Issue: 41

DOI: 10.1021/acs.jpcb.1c06902

Abstract

Cu(I) »4H-imidazolato complexes are excellent photosensitizers with broad and intense light absorption properties, based on an earth-abundant metal, and hold great promise as photosensitizers in artificial photosynthesis and for accumulation of redox equivalents. In this study, the excited-state relaxation dynamics of three novel heteroleptic Cu(I) »4H-imidazolato complexes with phenyl, tolyl, and mesityl side groups are systematically investigated by femtosecond and nanosecond time-resolved transient absorption spectroscopy and theoretical methods, complemented by steady-state absorption spectroscopy and (spectro)electrochemistry. After photoexcitation into the metal-to-ligand charge transfer (MLCT) and intraligand charge transfer absorption band, fast (0.6-1 »ps) intersystem crossing occurs into the triplet MLCT manifold. The triplet-state population relaxes via the geometrical planarization of the N-aryl rings on the Cu(I) 4H-imidazolato complexes. Depending on the initial Franck-Condon state, the remaining small singlet state population relaxes into two geometrically distinct minima geometries with similar energy, S1/2,relax and S3/4,relax. Subsequent ground-state recovery from S1/2,relax and internal conversion from S3/4,relax to S1/2,relax take place on a 100 »ps time scale. The internal conversion can be understood as hole transfer from a dyz-orbital to a dxz-orbital, which is accompanied with the structural reorganization of the coordination environment. Generally, the photophysical processes are determined by the steric hindrance of the side groups on the ligands. And the excited singlet-state pathways are dependent on the excitation wavelength.

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How to cite

APA:

Seidler, B., Sittig, M., Zens, C., Tran, J.H., Müller, C., Zhang, Y.,... Dietzek, B. (2021). Modulating the Excited-State Decay Pathways of Cu(I) 4 H-Imidazolate Complexes by Excitation Wavelength and Ligand Backbone. Journal of Physical Chemistry B, 125(41), 11498-11511. https://dx.doi.org/10.1021/acs.jpcb.1c06902

MLA:

Seidler, Bianca, et al. "Modulating the Excited-State Decay Pathways of Cu(I) 4 H-Imidazolate Complexes by Excitation Wavelength and Ligand Backbone." Journal of Physical Chemistry B 125.41 (2021): 11498-11511.

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