[(thf)5Ln(Ge9{Si(SiMe3)3}2)] (Ln = Eu, Sm, Yb): Capping Metalloid Germanium Cluster with Lanthanides

Klementyeva SV, Woern K, Schrenk C, Zhang M, Khusniyarov M, Schnepf A (2023)

Publication Type: Journal article

Publication year: 2023

Journal

Inorganic Chemistry American Chemical Society

DOI: 10.1021/acs.inorgchem.3c00165

Abstract

We report the synthesis of three neutral complexes with different coordination modes of a di-silylated metalloid germanium cluster to divalent lanthanides [(thf)5Ln(ηn-Ge9(Hyp)2)] (Ln = Yb (1, n = 1); Eu (2, n = 2, 3), Sm (3, n = 2, 3); Hyp = Si(SiMe3)3) by the salt metathesis of LnI2 with K2[Ge9(Hyp)2] in THF. The complexes were characterized by elemental analysis, nuclear magnetic resonance and UV-vis-NIR spectroscopy, and single-crystal X-ray diffraction. In thf solution, the formation of contact or solvate-separated ion pairs depending on the concentration is assumed. Compound 2 exhibits a blue luminescence typical for Eu2+. The solid-state magnetic measurements of compounds 2 and 3 confirm the presence of divalent europium and samarium, respectively.

Authors with CRIS profile

Minghui Zhang Naturwissenschaftliche Fakultät Marat Khusniyarov Department Chemie und Pharmazie

Involved external institutions

Eberhard Karls Universität Tübingen DE Germany (DE)

How to cite

APA:

Klementyeva, S.V., Woern, K., Schrenk, C., Zhang, M., Khusniyarov, M., & Schnepf, A. (2023). [(thf)5Ln(Ge9{Si(SiMe3)3}2)] (Ln = Eu, Sm, Yb): Capping Metalloid Germanium Cluster with Lanthanides. Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.3c00165

MLA:

Klementyeva, Svetlana V., et al. "[(thf)5Ln(Ge9{Si(SiMe3)3}2)] (Ln = Eu, Sm, Yb): Capping Metalloid Germanium Cluster with Lanthanides." Inorganic Chemistry (2023).

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