Synthesis and Properties of C2h-Symmetric BN-Heteroacenes Tailored through Aromatic Central Cores

Wang X, Zhang F, Gao J, Fu Y, Zhao W, Tang R, Zhang W, Zhuang X, Feng X (2015)

Publication Type: Journal article

Publication year: 2015

Journal

Journal of Organic Chemistry American Chemical Society

Book Volume: 80

Pages Range: 10127-10133

Journal Issue: 20

DOI: 10.1021/acs.joc.5b01718

Abstract

The 2-fold successive electrophilic borylation on one aromatic central core led to a series of C2h-symmetric BN-heteroacenes in excellent yields. For the first time, we introduced trimethylsilyl (TMS) as either leaving group or oriented group for efficiently improving the preparation of BN-embedded polycyclic aromatic hydrocarbons (PAHs). The physical properties of the as-synthesized BN-heteroacenes in either solid state or solution can be finely tuned through the position isomerization or the fused ring numbers of the aromatic central core.

Involved external institutions

Shanghai Jiao Tong University / 上海交通大学 CN China (CN) Hangzhou Normal University / 杭州师范大学 CN China (CN)

How to cite

APA:

Wang, X., Zhang, F., Gao, J., Fu, Y., Zhao, W., Tang, R.,... Feng, X. (2015). Synthesis and Properties of C2h-Symmetric BN-Heteroacenes Tailored through Aromatic Central Cores. Journal of Organic Chemistry, 80(20), 10127-10133. https://doi.org/10.1021/acs.joc.5b01718

MLA:

Wang, Xinyang, et al. "Synthesis and Properties of C2h-Symmetric BN-Heteroacenes Tailored through Aromatic Central Cores." Journal of Organic Chemistry 80.20 (2015): 10127-10133.

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