Chemical Approaches to Carbon-Based Metal-Free Catalysts

Liu D, Dai L, Lin X, Chen JF, Zhang J, Feng X, Muellen K, Zhu X, Dai S (2019)

Publication Type: Journal article, Review article

Publication year: 2019

Journal

Advanced Materials Wiley

Book Volume: 31

Article Number: 1804863

Journal Issue: 13

DOI: 10.1002/adma.201804863

Abstract

Highly active and durable catalysts play a key role in clean energy technologies. However, the high cost, low reserves, and poor stability of noble-metal-based catalysts have hindered the large-scale development of renewable energy. Owing to their low cost, earth abundance, high activity, and excellent stability, carbon-based metal-free catalysts (CMFCs) are promising alternatives to precious-metal-based catalysts. Although many synthetic methods based on solution, surface/interface, solid state, and noncovalent chemistries have been developed for producing numerous CMFCs with diverse structures and functionalities, there is still a lack of effective approaches to precisely control the structures of active sites. Therefore, novel chemical approaches are needed for the development of highly active and durable CMFCs that are capable of replacing precious-metal catalysts for large-scale applications. Herein, a comprehensive and critical review on chemical approaches to CMFCs is given by summarizing important advancements, current challenges, and future perspectives in this emerging field. Through such a critical review, our understanding of CMFCs and the associated synthetic processes will be significantly increased.

Involved external institutions

Beijing University of Chemical Technology CN China (CN) Technische Universität Dresden DE Germany (DE) Max-Planck-Institut für Polymerforschung (MPI-P) / Max Planck Institute for Polymer Research DE Germany (DE) Oak Ridge National Laboratory US United States (USA) (US)

How to cite

APA:

Liu, D., Dai, L., Lin, X., Chen, J.-F., Zhang, J., Feng, X.,... Dai, S. (2019). Chemical Approaches to Carbon-Based Metal-Free Catalysts. Advanced Materials, 31(13). https://doi.org/10.1002/adma.201804863

MLA:

Liu, Dong, et al. "Chemical Approaches to Carbon-Based Metal-Free Catalysts." Advanced Materials 31.13 (2019).

BibTeX: Download