Langner S, Perea Ospina JD, Zhang C, Li N, Brabec C (2019)
Publication Type: Authored book
Publication year: 2019
Publisher: CRC Press
ISBN: 9781315159294
This chapter introduces the approach to ab initio calculate the values based on computational methods, and a Figure of Merit to predict the microstructure stability of bulk heterojunction (BHJ) composites. It focuses on solute-liquid miscibility and solute-solute miscibility and explains the degradation mechanisms related to microstructure. The chapter provides a detailed insight into the theoretical, computational and experimental principles of mixing of organic semiconductors. The microstructure of a BHJ film is determined by the competition between thermodynamics and kinetics during the drying process. The chapter describes the M. L. Hansen solubility parameters (HSPs) can be visualized in a three dimensional coordinates system with the solubility parameters as axes. The mixing compatibility of a polymer and a fullerene is graphically represented by the values of thermodynamic variables when the equilibrium is established among the phases of a system.
APA:
Langner, S., Perea Ospina, J.D., Zhang, C., Li, N., & Brabec, C. (2019). The Relevance of Solubility and Miscibility for the Performance of Organic Solar Cells. CRC Press.
MLA:
Langner, Stefan, et al. The Relevance of Solubility and Miscibility for the Performance of Organic Solar Cells. CRC Press, 2019.
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