Visible-Light-Mediated Radical Arylations Using a Fluorescein- Derived Diazonium Salt: Reactions Proceeding via an Intramolecular Forth and Back Electron Transfer

Diesendorf N, Wenisch P, Oppl J, Heinrich M (2023)

Publication Type: Journal article

Publication year: 2023

Journal

Organic Letters American Chemical Society

DOI: 10.1021/acs.orglett.2c03877

Abstract

Functionalizations of arenes and alkenes via additive-free radical reactions using highly photosensitive, fluorescein-derived diazonium salts are described. The particular properties of the diazonium salts enable unique Meerwein-type carbohydroxylations of non-activated alkenes, which can be rationalized by a reaction mechanism involving forth and back electron transfer from and to the xanthene subunit of the fluorescein moiety.

Authors with CRIS profile

Nina Diesendorf Professur für Pharmazeutische Chemie Pia Wenisch Lehrstuhl für Pharmazeutische Chemie Markus Heinrich Professur für Pharmazeutische Chemie

How to cite

APA:

Diesendorf, N., Wenisch, P., Oppl, J., & Heinrich, M. (2023). Visible-Light-Mediated Radical Arylations Using a Fluorescein- Derived Diazonium Salt: Reactions Proceeding via an Intramolecular Forth and Back Electron Transfer. Organic Letters. https://doi.org/10.1021/acs.orglett.2c03877

MLA:

Diesendorf, Nina, et al. "Visible-Light-Mediated Radical Arylations Using a Fluorescein- Derived Diazonium Salt: Reactions Proceeding via an Intramolecular Forth and Back Electron Transfer." Organic Letters (2023).

BibTeX: Download