Büttner P, Scheler F, Döhler D, Barr M, Bosch M, Rey M, Yokosawa T, Hinz S, Maultzsch J, Spiecker E, Vogel N, Minguez Bacho I, Bachmann J (2022)
Publication Language: English
Publication Status: Published
Publication Type: Journal article, Original article
Publication year: 2022
Publisher: Elsevier Ltd
Book Volume: 103
Article Number: 107820
DOI: 10.1016/j.nanoen.2022.107820
Many modern types of solar cells that rely exclusively on earth-abundant non-toxic materials include interfaces between a heavier metal chalcogenide and another type of semiconductor. Often, the chemical (adhesion) and physical (charge transfer) characteristics of those interfaces are the defining factors for the final device performance. Here, we describe that a ZnS adhesion layer is not sufficient to prevent the dewetting of Sb2S3 upon annealing a thin layer of it on an oxidic surface if the substrate is not planar and features highly curved surfaces. An ALD-coated sacrificial capping layer of ZnO prevents the morphological rearrangements of Sb2S3 during thermal crystallization and can be removed subsequently. When implemented towards a photovoltaic p-i-n heterojunction, this strategy furnishes perfect conformality of the layer stack but unsatisfactory performance. The correlation of interface chemistry with the electrical properties and the device performance identifies a reducing effect of ZnO atomic layer deposition chemistry on the Sb2S3 surface as the cause of Zn diffusion into the light absorbing semiconductor. This deleterious doping can be prevented by a preliminary oxidative treatment of the Sb2S3 surface with ozone. When applied to a structured substrate consisting of ordered arrays of nanospheres, this approach yields the first ever concentric p-i-n heterojunction solar cells with photonic light trapping effect—a geometry which in comparison with standard scattering layers'on top’ inherently generates a very large refractive index contrast. In the red part of the visible spectrum, light absorption amounts to the value expected with four passes through a planar layer of the thickness used here (35 nm Sb2S3). This effect allows us to demonstrate >5% overall solar energy conversion efficiency with only 35 nm of a simple light absorber phase that uses no toxic, rare materials.
APA:
Büttner, P., Scheler, F., Döhler, D., Barr, M., Bosch, M., Rey, M.,... Bachmann, J. (2022). Continuous, crystalline Sb2S3 ultrathin light absorber coatings in solar cells based on photonic concentric p-i-n heterojunctions. Nano Energy, 103. https://doi.org/10.1016/j.nanoen.2022.107820
MLA:
Büttner, Pascal, et al. "Continuous, crystalline Sb2S3 ultrathin light absorber coatings in solar cells based on photonic concentric p-i-n heterojunctions." Nano Energy 103 (2022).
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