Local Structural Investigation of (Ba,Ca)(Zr,Ti)O3 and Ca(Zr,Ti)O3 by X-Ray Fluorescence Holography

Yamamoto Y, Kimura K, Gadelmawla A, Kawamura K, Sugimoto H, Liu D, Li Q, Yan Q, Khansur NH, Happo N, Kakimoto KI, Webber KG, Hayashi K (2022)

Publication Type: Journal article

Publication year: 2022

Journal

physica status solidi (b) Wiley

DOI: 10.1002/pssb.202100609

Abstract

Analyses of the local structures around Zr doped in ferroelectric (Ba,Ca)(Zr,Ti)O3 (BCZT) and paraelectric Ca(Zr,Ti)O3 (CZT) are carried out by X-ray fluorescence holography. The images of the cations at the A and B sites of these ABO3 perovskites are clearly reconstructed from the measured holograms. In the real space images, a 0.2 Å outward displacement of the nearest Ba and Ca is observed in the atomic images of both BCZT and CZT, attributable to the difference in the ionic radius between Zr4+ and Ti4+. In addition, the first-neighboring Ti in BCZT is displaced inward by 0.5 Å, whereas no such displacement is observed in CZT. This shift of Ti in BCZT appears due to the large strain of the local lattice, and it can affect to the piezoelectric response of BCZT.

Authors with CRIS profile

Ahmed Gadelmawla Lehrstuhl für Glas und Keramik Neamul Hayet Khansur Lehrstuhl für Glas und Keramik Kyle Grant Webber Professur für Werkstoffwissenschaften (Funktionskeramik)

Additional Organisation(s)

Graduiertenkolleg 2495 Energiekonvertierungssysteme: von Materialien zu Bauteilen (Energy Conversion Systems: From Materials to Devices)

Involved external institutions

Nagoya Institute of Technology / 名古屋工業大学 Nagoya Kōgyō Daigaku JP Japan (JP) Tsinghua University CN China (CN) Hiroshima City University / 広島市立大学 JP Japan (JP)

How to cite

APA:

Yamamoto, Y., Kimura, K., Gadelmawla, A., Kawamura, K., Sugimoto, H., Liu, D.,... Hayashi, K. (2022). Local Structural Investigation of (Ba,Ca)(Zr,Ti)O3 and Ca(Zr,Ti)O3 by X-Ray Fluorescence Holography. physica status solidi (b). https://doi.org/10.1002/pssb.202100609

MLA:

Yamamoto, Yuta, et al. "Local Structural Investigation of (Ba,Ca)(Zr,Ti)O3 and Ca(Zr,Ti)O3 by X-Ray Fluorescence Holography." physica status solidi (b) (2022).

BibTeX: Download