Ionothermal Synthesis of Sulfidobismuth spiro-Dicubane Cations

Knies M, Ruck M (2022)

Publication Type: Journal article

Publication year: 2022

Journal

ChemistryOpen Wiley Open Access: Chemistry Open / Wiley

Book Volume: 11

Article Number: e202100145

Journal Issue: 2

DOI: 10.1002/open.202100145

Abstract

Bi2S3 was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl3 (BMIm=1-n-butyl-3-methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air-sensitive crystals of Na(Bi7S8)[S(AlCl3)3]2[AlCl4]2 (1) precipitated. X-ray diffraction on single-crystals of 1 revealed a triclinic crystal structure that contains (Bi7S8)5+ spiro-dicubanes, [S(AlCl3)3]2− tetrahedra triples, isolated [AlCl4]− tetrahedra, and sodium cations.

Involved external institutions

Technische Universität Dresden DE Germany (DE)

How to cite

APA:

Knies, M., & Ruck, M. (2022). Ionothermal Synthesis of Sulfidobismuth spiro-Dicubane Cations. ChemistryOpen, 11(2). https://dx.doi.org/10.1002/open.202100145

MLA:

Knies, Maximilian, and Michael Ruck. "Ionothermal Synthesis of Sulfidobismuth spiro-Dicubane Cations." ChemistryOpen 11.2 (2022).

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