In situ study of non-equilibrium solidification of CoCrFeNi high-entropy alloy and CrFeNi and CoCrNi ternary suballoys

Andreoli AF, Shuleshova O, Witusiewicz VT, Wu Y, Yang Y, Ivashko O, Dippel AC, Zimmermann M, Nielsch K, Kaban I (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Acta Materialia Elsevier

Book Volume: 212

Article Number: 116880

DOI: 10.1016/j.actamat.2021.116880

Abstract

The solidification behavior of the CoCrFeNi high-entropy alloy and the ternary CrFeNi and CoCrNi medium-entropy suballoys has been studied in situ using high-speed video and synchrotron X-ray diffraction on electromagnetically levitated samples. In all alloys, the formation of a primary metastable bcc phase was observed if the melt was sufficiently undercooled. The delay time for the onset of the nucleation of the stable fcc phase, occurring within bcc crystals, is inversely proportional to the melt undercooling. The experimental findings are corroborated by thermodynamic calculations of stable and metastable phase diagrams for the (CoCrNi)-Fe section. Crystal-growth velocities for the CrFeNi, CoCrNi, and CoCrFeNi medium- and high-entropy alloys extracted from the high-speed video sequences in the present study are comparable to the literature data for Fe-rich Fe-Ni and Fe-Cr-Ni alloys, evidencing the same crystallization kinetics. The effect of melt undercooling on the microstructure of solidified samples is analyzed and discussed.

Involved external institutions

Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden e.V. (IFW) / Leibniz Institute for Solid State and Materials Research Dresden DE Germany (DE) Access e.V. DE Germany (DE) Deutsches Elektronen-Synchrotron DESY DE Germany (DE)

How to cite

APA:

Andreoli, A.F., Shuleshova, O., Witusiewicz, V.T., Wu, Y., Yang, Y., Ivashko, O.,... Kaban, I. (2021). In situ study of non-equilibrium solidification of CoCrFeNi high-entropy alloy and CrFeNi and CoCrNi ternary suballoys. Acta Materialia, 212. https://doi.org/10.1016/j.actamat.2021.116880

MLA:

Andreoli, Angelo F., et al. "In situ study of non-equilibrium solidification of CoCrFeNi high-entropy alloy and CrFeNi and CoCrNi ternary suballoys." Acta Materialia 212 (2021).

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