Coordination chemistry of f-block metal ions with ligands bearing bio-relevant functional groups
Goetzke L, Schaper G, Maerz J, Kaden P, Huittinen N, Stumpf T, Kammerlander KKK, Brunner E, Hahn P, Mehnert A, Kersting B, Henle T, Lindoy LF, Zanoni G, Weigand JJ (2019)
Publication Type: Journal article, Review article
Publication year: 2019
Journal
Book Volume: 386
Pages Range: 267-309
DOI: 10.1016/j.ccr.2019.01.006
Abstract
Over recent decades there has been a great deal of interest and associated research into aspects of the f-block (lanthanide and actinide) metal chemistry of naturally-occurring ligands, such as proteins, peptides, porphyrins and related tetraaza derivatives as well as synthetically modified natural ligands and solely synthetic ligand systems incorporating bio-relevant functional groups. In this review, we present a wide-ranging overview of published work spanning the above areas, with emphasis on selected biological, medical and environmental aspects. Systems capable of discriminating between metal ions from within, or between, the lanthanide and actinide groups are also discussed including the design and synthesis of biomimetic radionuclide chelators and radionuclide decorporation agents as well as solid adsorbent materials for the uptake of radionuclides from the environment and elsewhere. Thus, the interaction of the f-group elements with a range of biopolymers, including systems based on cellulose, chitin, chitosan, humic substances as well as a range of synthetic model systems is also presented. Other applications include the synthesis of new luminescent materials, including luminescent probes and luminescent metal coordination polymers exhibiting unusual photophysical properties as well as systems showing potential for use in the development of new MRI imaging agents.
Involved external institutions
Technische Universität Dresden
Germany (DE)
Helmholtz-Zentrum Dresden-Rossendorf (HZDR)
Germany (DE)
Università degli Studi di Pavia
Italy (IT)
Universität Leipzig
Germany (DE)
University of Sydney (USYD)
Australia (AU)
Germany (DE)
Helmholtz-Zentrum Dresden-Rossendorf (HZDR)
Germany (DE)
Università degli Studi di Pavia
Italy (IT)
Universität Leipzig
Germany (DE)
University of Sydney (USYD)
Australia (AU)
How to cite
APA:
Goetzke, L., Schaper, G., Maerz, J., Kaden, P., Huittinen, N., Stumpf, T.,... Weigand, J.J. (2019). Coordination chemistry of f-block metal ions with ligands bearing bio-relevant functional groups. Coordination Chemistry Reviews, 386, 267-309. https://doi.org/10.1016/j.ccr.2019.01.006
MLA:
Goetzke, Linda, et al. "Coordination chemistry of f-block metal ions with ligands bearing bio-relevant functional groups." Coordination Chemistry Reviews 386 (2019): 267-309.
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