The Mechanism of Cyclodehydrofluorination on γ-Alumina

Sharapa D, Steiner AK, Amsharov K (2018)

Publication Type: Journal article

Publication year: 2018

Journal

physica status solidi (b) Wiley

Book Volume: 255

Article Number: 1800189

Journal Issue: 12

DOI: 10.1002/pssb.201800189

Abstract

The cyclodehydrofluorination of fluorinated arenes on the thermally activated γ-aluminum oxide is found to be very effective for the rational synthesis of nanographenes and related carbon based nanostructures by bottom-up approach. In this work we performed an extended DFT study of cyclodehydrofluorination which shed light on the mechanism of this important transformation. The fundamental mechanistic insights provide the guidelines for further improvement of the synthesis of well-defined nanographenes via CF bond activation.

Authors with CRIS profile

Ann-Kristin Steiner Lehrstuhl für Organische Chemie II Konstantin Amsharov Lehrstuhl für Organische Chemie II

Involved external institutions

Karlsruhe Institute of Technology (KIT) DE Germany (DE)

How to cite

APA:

Sharapa, D., Steiner, A.-K., & Amsharov, K. (2018). The Mechanism of Cyclodehydrofluorination on γ-Alumina. physica status solidi (b), 255(12). https://doi.org/10.1002/pssb.201800189

MLA:

Sharapa, Dmitry, Ann-Kristin Steiner, and Konstantin Amsharov. "The Mechanism of Cyclodehydrofluorination on γ-Alumina." physica status solidi (b) 255.12 (2018).

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