Tailoring adsorption induced switchability of a pillared layer MOF by crystal size engineering

Abylgazina L, Senkovska I, Ehrling S, Bon V, Petkov PS, Evans JD, Krylova S, Krylov A, Kaskel S (2021)

Publication Type: Journal article

Publication year: 2021

Journal

CrystEngComm Royal Society of Chemistry

Book Volume: 23

Pages Range: 538-549

Journal Issue: 3

DOI: 10.1039/d0ce01497d

Abstract

The pillared layer framework DUT-8(Zn) (Zn2(2,6-ndc)2(dabco), 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo-[2.2.2]-octane, DUT = Dresden University of Technology) is a prototypical switchable MOF, showing characteristic adsorption and desorption induced open phase (op) to closed phase (cp) transformation associated with huge changes in cell volume. We demonstrate switchability strongly depends on a framework-specific critical particle size (dcrit). Superposed, the solvent removal process (pore desolvation stress contracting the framework) significantly controls the cp/op ratio after desolvation and, subsequently, the adsorption induced switchability characteristics of the system. After desolvation, the dense cp phase of DUT-8(Zn) shows no adsorption-induced reopening and therefore is non-porous for N2 at 77 K and CO2 at 195 K. However, polar molecules with a higher adsorption enthalpy, such as chloromethane at 249 K and dichloromethane (DCM) at 298 K can reopen the macro-sized crystals upon adsorption. For macro-sized particles, the outer surface energy is negligible and only the type of metal (Zn, Co, Ni) controls the DCM-induced gate opening pressure. The node hinge stiffness increases from Zn to Ni as confirmed by DFT calculations, X-ray crystal structural analysis, and low frequency Raman spectroscopy. This softer Zn-based node hinges and overall increased stabilization of cp vs. op phase shift the critical particle size at which switchability starts to become suppressed to even lower values (dcrit < 200 nm) as compared to the Ni-based system (dcrit ≈ 500 nm). Hence, the three factors affecting switchability (energetics of the empty host, (Eop-Ecp) (I), particle size (II), and desolvation stress (III)) appear to be of the same order of magnitude and should be considered collectively, not individually.

Involved external institutions

Technische Universität Dresden DE Germany (DE) Sofia University "St. Kliment Ohridski" / Софийски университет "Св. Климент Охридски" BG Bulgaria (BG) Russian Academy of Sciences / Росси́йская акаде́мия нау́к (RAS) RU Russian Federation (RU)

How to cite

APA:

Abylgazina, L., Senkovska, I., Ehrling, S., Bon, V., Petkov, P.S., Evans, J.D.,... Kaskel, S. (2021). Tailoring adsorption induced switchability of a pillared layer MOF by crystal size engineering. CrystEngComm, 23(3), 538-549. https://dx.doi.org/10.1039/d0ce01497d

MLA:

Abylgazina, Leila, et al. "Tailoring adsorption induced switchability of a pillared layer MOF by crystal size engineering." CrystEngComm 23.3 (2021): 538-549.

BibTeX: Download