Generalized Domino-Driven Synthesis of Hollow Hybrid Carbon Spheres with Ultrafine Metal Nitrides/Oxides

Xu F, Ding B, Qiu Y, Dong R, Zhuang W, Xu X, Han H, Yang J, Wei B, Wang H, Kaskel S (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Matter Cell Press

Book Volume: 3

Pages Range: 246-260

Journal Issue: 1

DOI: 10.1016/j.matt.2020.05.012

Abstract

We have demonstrated an ingenious one-pot aqueous domino-driven synthesis toward hollow hybrid spheres with ultrafine metal nitrides/oxides in hollow carbon cavity. The micelle-interfacial copolymerization is applied for shell formation, while the copolymerization-generated H+ spontaneously triggers oxometallate condensation for encapsulation. By regulating the synthetic conditions, the encapsulated metal species can be well tailored with different sizes/contents (nanocluster to several nanometers) and compositions (VN, VO, MoN, WN, bimetal-based nitrides). The ultrafine VN confined in hollow carbon exhibits excellent potassium storage performance.

Involved external institutions

Northwestern Polytechnical University / 西北工业大学 (NPU/NWPU) CN China (CN) Technische Universität Dresden DE Germany (DE) University of Delaware (UDEL) US United States (USA) (US)

How to cite

APA:

Xu, F., Ding, B., Qiu, Y., Dong, R., Zhuang, W., Xu, X.,... Kaskel, S. (2020). Generalized Domino-Driven Synthesis of Hollow Hybrid Carbon Spheres with Ultrafine Metal Nitrides/Oxides. Matter, 3(1), 246-260. https://doi.org/10.1016/j.matt.2020.05.012

MLA:

Xu, Fei, et al. "Generalized Domino-Driven Synthesis of Hollow Hybrid Carbon Spheres with Ultrafine Metal Nitrides/Oxides." Matter 3.1 (2020): 246-260.

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