Messelberger J, Pinter P, Heinemann FW, Munz D (2021)
Publication Type: Journal article
Publication year: 2021
Book Volume: 31
Pages Range: 471-474
Journal Issue: 4
DOI: 10.1016/j.mencom.2021.07.011
A well defined intermolecular toluene complex of lead(ii) supported by a pincer-type saNHC (saturated N-heterocyclic carbene) ligand was prepared through deprotonation of the bis(irnidazolinium) salt with Pb[N(SiMe3)(2)](2) or metalation of the free carbene and subsequent salt metathesis with Tl(OTf), followed by crystallization from toluene. Combined computational and experimental results indicate that noncovalent interactions with the lead atom (sigma-hole type interaction, dispersion) and the diisopropylphenyl side groups of the ligand (dispersion) stabilize the complex.
APA:
Messelberger, J., Pinter, P., Heinemann, F.W., & Munz, D. (2021). A lead(II) toluene complex. Mendeleev Communications, 31(4), 471-474. https://doi.org/10.1016/j.mencom.2021.07.011
MLA:
Messelberger, Julian, et al. "A lead(II) toluene complex." Mendeleev Communications 31.4 (2021): 471-474.
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