Transition-metal free synthesis of N-aryl carbazoles and their extended analogs

Feofanov M, Akhmetov V, Takayama R, Amsharov K (2021)

Publication Type: Journal article

Publication year: 2021

Journal

Organic & Biomolecular Chemistry Royal Society of Chemistry

DOI: 10.1039/d1ob00940k

Abstract

Herein, we describe a facile synthesis of N-arylated carbazoles via ladderization of fluorinated oligophenylenes. The reaction consists of two subsequent nucleophilic substitutions triggered by an electronic transfer from dimsyl anions. The reaction allows the effective one-pot formation of at least six C-N bonds with pronounced selectivity to the C-F bond placement.

Authors with CRIS profile

Vladimir Akhmetov Lehrstuhl für Organische Chemie II Ryo Takayama Lehrstuhl für Organische Chemie II Konstantin Amsharov

Involved external institutions

Martin-Luther-Universität Halle-Wittenberg (MLU) DE Germany (DE)

How to cite

APA:

Feofanov, M., Akhmetov, V., Takayama, R., & Amsharov, K. (2021). Transition-metal free synthesis of N-aryl carbazoles and their extended analogs. Organic & Biomolecular Chemistry. https://doi.org/10.1039/d1ob00940k

MLA:

Feofanov, Mikhail, et al. "Transition-metal free synthesis of N-aryl carbazoles and their extended analogs." Organic & Biomolecular Chemistry (2021).

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