Electrochemistry of Ru(edta) complexes relevant to small molecule transformations: Catalytic implications and challenges
Chatterjee D, Oszajca M, Katafias A, van Eldik R (2021)
Publication Type: Journal article, Review article
Publication year: 2021
Journal
Book Volume: 436
Article Number: 213773
DOI: 10.1016/j.ccr.2021.213773
Abstract
Electrochemistry of Ru(edta) complexes (edta4− = ethylenediaminetetraacetate) progressed over a period of several decades, with significant increase in understanding of the electro-catalytic processes involving the substrate coordinated to the metal center. While electrochemistry studies of many Ru(edta) complexes were published in several papers, no attempt has been made to provide a comprehensive and systematic overview of its electrochemical properties, evaluating its application to catalytic electrochemical transformation of small molecules. In this article, results of the electrochemical studies of both mononuclear and binuclear complexes of Ru(edta) are reviewed with regard to electron-transfer reaction mechanism and activity. Their potential to act as redox mediators or catalysts in electrochemical transformations of small molecules and enzymatic reactions, are highlighted. This review aims to contribute to the mechanistic understanding of Ru(edta) complexes in catalysis of such electrochemical transformations.
Authors with CRIS profile
Involved external institutions
The University of Burdwan
India (IN)
Jagiellonian University / Uniwersytet Jagielloński (UJ)
Poland (PL)
Nicolaus Copernicus University (NCU) / Uniwersytet Mikołaja Kopernika w Toruniu (UMK)
Poland (PL)
India (IN)
Jagiellonian University / Uniwersytet Jagielloński (UJ)
Poland (PL)
Nicolaus Copernicus University (NCU) / Uniwersytet Mikołaja Kopernika w Toruniu (UMK)
Poland (PL)
How to cite
APA:
Chatterjee, D., Oszajca, M., Katafias, A., & van Eldik, R. (2021). Electrochemistry of Ru(edta) complexes relevant to small molecule transformations: Catalytic implications and challenges. Coordination Chemistry Reviews, 436. https://doi.org/10.1016/j.ccr.2021.213773
MLA:
Chatterjee, Debabrata, et al. "Electrochemistry of Ru(edta) complexes relevant to small molecule transformations: Catalytic implications and challenges." Coordination Chemistry Reviews 436 (2021).
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