A valence tautomeric cobalt-dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides

Mörtel M, Seller M, Heinemann FW, Khusniyarov M (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Dalton Transactions Royal Society of Chemistry

Book Volume: 49

Pages Range: 17532-17536

Journal Issue: 48

DOI: 10.1039/d0dt03771k

Abstract

Here, we synthesized a valence tautomeric cobalt-dioxolene complex featuring a protected anchoring group. At room temperature, the complex reveals a nearly pure low-spin-Co(III)-catecholate state in the solid state, but a nearly pure high-spin-Co(II)-semiquinonate state in toluene solution. Thermal switchability of the complex in solution and in the solid state is investigated.

Authors with CRIS profile

Max Mörtel Lehrstuhl für Anorganische und Allgemeine Chemie Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Marat Khusniyarov Lehrstuhl für Bioanorganische Chemie

How to cite

APA:

Mörtel, M., Seller, M., Heinemann, F.W., & Khusniyarov, M. (2020). A valence tautomeric cobalt-dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides. Dalton Transactions, 49(48), 17532-17536. https://doi.org/10.1039/d0dt03771k

MLA:

Mörtel, Max, et al. "A valence tautomeric cobalt-dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides." Dalton Transactions 49.48 (2020): 17532-17536.

BibTeX: Download