Quantifying the Covalent Functionalization of Black Phosphorus

Wild S, Xuan Thong Dinh , Maid H, Hauke F, Abellán G, Hirsch A (2020)


Publication Type: Journal article

Publication year: 2020

Journal

DOI: 10.1002/anie.202008646

Abstract

A straightforward quantification method to consistently determine the overall functionalization degree of covalently modified two-dimensional (2D) black phosphorus (BP) by Raman spectroscopy has been carried out. Indeed, the successful reductive methylation of the BP lattice using sodium intercalation compounds and exhibiting different functionalization degrees has been demonstrated by P-31-magic angle spinning (MAS) NMR spectroscopy. Furthermore, the correlation of P-31-MAS NMR spectroscopy and statistical Raman spectroscopy (SRS) revealed the first method to determine the functionalization degree of BP solely by evaluating the intensities of distinct peaks in the Raman spectra of the covalently modified material, in a similar way to the widely employed I-D/I-G ratio of graphene research.

Authors with CRIS profile

How to cite

APA:

Wild, S., Xuan Thong Dinh, ., Maid, H., Hauke, F., Abellán, G., & Hirsch, A. (2020). Quantifying the Covalent Functionalization of Black Phosphorus. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202008646

MLA:

Wild, Stefan, et al. "Quantifying the Covalent Functionalization of Black Phosphorus." Angewandte Chemie International Edition (2020).

BibTeX: Download